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Mononuclear and dinuclear osmium(II) compounds containing 2,2'-bipyridine and 3,5-bis(pyridin-2-yl)-1,2,4-triazole: synthesis, electrochemistry, absorption spectra, and luminescence properties

โœ Scribed by Barigelletti, Francesco.; De Cola, Luisa.; Balzani, Vincenzo.; Hage, Ronald.; Haasnoot, Jaap G.; Reedijk, Jan.; Vos, Johannes G.


Book ID
127130011
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
642 KB
Volume
30
Category
Article
ISSN
0020-1669

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Mono- and dinuclear rhodium(I) complexes
โœ Maria P. Garcia; Marta Martin; Luis A. Oro ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 500 KB

Reactions of [RhClL] (L,=diolefin or (CO)(PPh,)) with the deprotonated form of the ligand 3,5bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh&)(bpt)]. Cationic, mono-and dinuclear species of formulae [Rh&.)(Hbpt)]+, [{Rhb}\*(bpt)]+ and [{Rh&.}@bpt)]\*+, where b=diolefi