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Photooxidation of Sulfides to Sulfoxides Mediated by Tetra-O-Acetylriboflavin and Visible Light

✍ Scribed by Jitka Dad'ová; Dr. Eva Svobodová; Dr. Marek Sikorski; Prof. Dr. Burkhard König; Dr. Radek Cibulka

Book ID
112019223
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
237 KB
Volume
4
Category
Article
ISSN
1867-3880

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Under visible light irradiation, the carbonyl ruthenium(II) porphyrin complexes efficiently catalyze the selective oxidation of sulfides to sulfoxides with iodobenzene diacetate [PhI(OAc) 2 ] as the oxygen source. Various thioanisoles and allylic sulfides were oxidized to the corresponding sulfoxide