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Chemoselective and efficient oxidation of sulfides to sulfoxides mediated by trimethylsilyl chloride and superoxide via a trimethylsilylperoxy radical

โœ Scribed by Yao-Jung Chen; Yu-Ping Huang


Book ID
108379848
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
130 KB
Volume
41
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Efficient oxidation of sulfides to the s
โœ Yong Hae Kim; Dae Chul Yoon ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

Various sulfides were found to react with a sulfinylperoxy intermediate yenerdted in situ by the treatment of Z-nitrobenzenesulfinyl --chloride with superoxide at, -25 OC in acetonitrile to afford the corresponding sulfoxides selectively in excellent yields toyether with traceable amount of the sulf