Photometric study of iron-resacetophenone-oxime complex
β Scribed by Raja Reddy, G. ;Kadarmandalgi, S. G. ;Murthy, A. S. R.
- Book ID
- 112979809
- Publisher
- Springer-Verlag
- Year
- 1964
- Tongue
- English
- Weight
- 292 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0370-0089
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The iron(II) complex of H 2 L 14-dimethyl-4, 7, 10, 13-tetraazahexadeca-(H L Ο 3, 2 3,13-diene-2,15-dione dioxime, Coord. Chem. Rev., 33, 87 (1980)) is oxidized by periodate very rapidly in the range pH 2.0-7.0, and the kinetics of the reaction has been followed by stoppedflow spectrophotometry at 3
## Complexes of the type Fe(qo), have been prepared, where qoH = I nitroso-2-naphthol, 2-nitroso-I -naphthol, phenanthrene-9, IO-quinonemono-oxime, 5-methoxy-2-nitrosophenol, 5-methyl-2-nitrosophenol and 4,5-dimethyl-2-nitrosophenol. Some of the complexes react with hydrochloric acid to give FeCl(qo