Photolytic studies on 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl, a stable nitroxide free radical
β Scribed by Keana, John F. W.; Dinerstein, Robert J.; Baitis, Friedhelm
- Book ID
- 125540539
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 367 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
To enrich the limited set of isonitriles typically employed, 4-isocyano-2,2,6,6-teramethylpiperidin-1-oxyl (1) is proposed as an isonitrile bearing a nitroxyl moiety. Isocyanide 1 was used in some reactions characteristic of isonitriles. Isoselenocyanate, amides (products of Passerini and Ugi reacti
The exposure of 4-hydroxy-2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPOL) to hydroxyl radical ((.)OH) led to the appearance of a new triplet ESR signal along with a reduction in the intensity of the TEMPOL signal. The observed spectrum was in good agreement with the spectrum simulated with 4-oxo-2,2,6