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4-Isocyano-2,2,6,6-tetramethylpiperidin- 1-oxyl: A Valuable Precursor for the Synthesis of New Nitroxides

✍ Scribed by Zakrzewski, Jerzy; Jezierska, Julia; Hupko, Jarosław

Book ID
120516561
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
63 KB
Volume
6
Category
Article
ISSN
1523-7060

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4-Isocyano-2,2,6,6-tetramethylpiperidin-
4-Isocyano-2,2,6,6-tetramethylpiperidin- 1-oxyl: A Valuable Precursor for the Synthesis of New Nitroxides
✍ Zakrzewski, Jerzy; Jezierska, Julia; Hupko, Jarosław 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 63 KB

To enrich the limited set of isonitriles typically employed, 4-isocyano-2,2,6,6-teramethylpiperidin-1-oxyl (1) is proposed as an isonitrile bearing a nitroxyl moiety. Isocyanide 1 was used in some reactions characteristic of isonitriles. Isoselenocyanate, amides (products of Passerini and Ugi reacti