Photolysis of tert-butyl peroxylaurate
✍ Scribed by Davis, John J.; Miller, John G.
- Book ID
- 127076632
- Publisher
- American Chemical Society
- Year
- 1977
- Tongue
- English
- Weight
- 161 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0002-7863
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The CIDEP of tert.butyl radicals during photolysis of di-tert.butyl ketone is analysed. Triplet and radical pair mechanism induce enhanced absorption and an E/A multiplet effect at the initiation stage. The F-pair polarization reflects S-To and S-T+ mixing due to a solvent dependent indirect exchang
## Abstract The photolysis of a heptane solution of 2,6‐di‐__tert__‐butyl‐4‐__tert__‐butylperoxy‐4‐methyl‐ 2,5‐cyclohexadienone (1) with light of 360–480 nm in the presence of 2,6‐di‐__tert__‐butyl‐4‐methylphenol or 2,4,6‐tri‐__tert__‐butylphenol gives rise to their corresponding phenoxyls in a rea