Photolysis of Alkyl Nitrites. I. tert -Butyl Nitrite
โ Scribed by McMillan, G. R.
- Book ID
- 126191797
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 590 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The rate of decomposition of s-butyl nitrite (SBN) has been studied in the absence (130-160ยฐC) and presence (160-200ยฐC) of NO. Under the former conditions, for low concentrabions of SBN (6 x 10-5 -lO-4M) and small extents of reaction (-l.5yc), the first-order homogeneoris rates of acetaldehyde (AcH)
Recently, Mackor et al. reported the formation of dialkyl nitroxides and alkoxy-alkyl-nitroxides during the photolysis of alkyl nitrites in hydrocarbon solvents. (1) These radicals, which were characterised by their electron spin resonance spectra, showed nitrogen hyperfine splitting constants of ap