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Very low pressure photolysis of tert-butyl nitrite at 248 nm

✍ Scribed by Paula L. Trevor; David M. Golden

Book ID
103492673
Publisher
Elsevier Science
Year
1983
Weight
306 KB
Volume
23
Category
Article
ISSN
0047-2670

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The very-low-pressure pyrolysis (VLPP) o
The very-low-pressure pyrolysis (VLPP) of n-propyl nitrate, tert-butyl nitrite, and methyl nitrite. Rate constants for some alkoxy radical reactions
✍ G. David Mendenhall; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1975 πŸ› John Wiley and Sons 🌐 English βš– 527 KB

The pyrolysis of n-propyl nitrate and tert-butyl nitrite at very low pressures (VLPP technique) is reported. For the reaction n-PrON02 A nPrO + NO2 the high-pressure rate expression at 300"K, log k, (sec-l) = 16.5 -40.0 kcal/mole/2.3 RT, is derived. The reaction tert-BuONO -% tert-BuO + N O was stud