The photolysis of t-butyl, isopropyl and ethyl nitrites at 254 nm
β Scribed by M.I. Christie; P.M. Hetherington
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 802 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0047-2670
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π SIMILAR VOLUMES
The photolysis of C2H51 in a glassy salt matrix (5M, 7.5M, 10M) of aqueous LiCl a t 77 K with light of X = 254 nm has been conducted, product analysis being by ESR and UV spectroscopy. The electrolytic medium causes the ionization of product HI, and I-concentrations can be continuously determined. D
The alkyl nitrites, C 2 H 5 0 N 0 , n -C 3 H 7 0 N 0 , n-C4HgON0, and i -C 4 H g O N 0 were photolyzed at 23Β°C in the presence of "NO at 366-nm incident radiation. The quantum yields of the corresponding isotopically-enriched alkyl nitrites were measured by mass spectrometry. The results indicated t
## Abstract The photolysis was investigated at 313 nm wavelength, 253β529 K temperatures, and 4 Γ 10^β11^β2 Γ 10^β9^ molΒ·photon/cm^2^Β·sec light intensities by determining the quantum yields of 20 reaction products. Primary quantum yields for the seven primary processes and rate constant ratios, rat