Photolysis of Alkyl Aryl Sulfoxides: α-Cleavage, Hydrogen Abstraction, and Racemization 1
✍ Scribed by Guo, Yushen; Jenks, William S.
- Book ID
- 120204968
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 258 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
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Synthesis of α,β-Unsaturated Sulfoxides and Aryl 1,2-x-Fused onto Furan Rings. -ortho-Quinones react non-uniformly with α-phosphoryl sulfoxide (II) to furnish mono-olefins [cf. (III)] or fused dihydrofuran derivatives [cf. (V), (VII)]. Contrary, the p-quinones (VIII) react with (II) in the usual ma