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ChemInform Abstract: Copper-Catalyzed Intramolecular Hydroalkoxylation of α-(1-Hydroxy-1-alkyl- and -aryl)methylallenoates by a 5-endo Mode for Preparation of 2-Alkyl- and 2-Aryl-2,5-dihydrofurans.

✍ Scribed by Sanghyuck Kim; Phil Ho Lee

Book ID: 112044234
Publisher: John Wiley and Sons
Year: 2012
Weight: 26 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201220093

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✍ Kim, Sanghyuck; Lee, Phil Ho 📂 Article 📅 2011 🏛 American Chemical Society 🌐 English ⚖ 673 KB

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ChemInform Abstract: Synthesis of 2-Alkyl- and Aryl-3-ethoxycarbonyl-2,5-dihydrofurans Through Gold-Catalyzed Intramolecular Hydroalkoxylation.

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## Abstract It provides an efficient approach to 2,5‐dihydrofurans of type (II).

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ChemInform Abstract: Chemodivergent Synthesis of 7-Aryl/alkyl-6-hydroxy-1,4-oxazepan-5-ones and 2-[Aryl/alkyl(hydroxy)methyl]morpholin-3-ones from a Common Epoxyamide Precursor.

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## Abstract Mixture of oxiranes (I), which are difficult to separate (no details given), allow a regiospecific synthesis of oxazepanones and morpholinones.

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