Photoisomerization of bicyclo[3.2.1]octadiene
β Scribed by Sauers, Ronald R.; Shurpik, Anton
- Book ID
- 120469716
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 520 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Bicyclo[3.2.l]octadienones with the general structure & photoisomerize to ketenes 4 and give products derived therefrom.ls3 The corresponding 3,4-benzo&tadienones 2 undergo reversible 1,3-acyl shifts ($ti,$).4 We now wish to report that the other possible (i.e., 6,7-) benzo derivatives of &, undergo
Below -60' in FSOaH/SOzClF the nonamethyl bicyclo[3.2.1 loctadien-Pyl cation J, undergoes two degenerate rearrangements, circumambulation' and a 1,2-shift of the methano bridge.2 The first of these processes is much faster than the second, and is nmr-observable,' whereas the second process was detec