✦ LIBER ✦

Photoionization of molecules in low temperature glasses

✍ Scribed by J.T. Richards; J.K. Thomas

Publisher: Elsevier Science
Year: 1971
Tongue: English
Weight: 407 KB
Volume: 8
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(71)80563-8

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✦ Synopsis

Trapped electrons have been produced in ethanol and 3 MH glass-s at 77*K by the photoionization of TMPD, using pulses of 3471A light from 3 ruby laser. Time dependent absorption spectra are observed which are compared to similar data obtained by pulse radio!ysis. It is concluded that similar electron trapping takes place in both cases and that the electrons are trapped in fortuitous arrangements of the solvent molecules in the matrix, and that the rearrangement of the solvent in the traps gives rise to the spectral changes.

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