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Crystallite clusters of syn-bimanes in low-temperature, low-polarity glasses

✍ Scribed by R. Giniger; E.M. Kosower


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
407 KB
Volume
140
Category
Article
ISSN
0009-2614

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✦ Synopsis


Aggregation of monomeric syn-bimanes (1,5-diazabicyclo [ 3.3.01 octa-3,6-dien-2,8diones) via dimers or n-mers into crystallites (organized clusters) can be induced by appropriate solvents at 77 K and monitored by emission spectra and radiative rates.


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Photoionization of molecules in low temp
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Trapped electrons have been produced in ethanol and 3 MH glass-s at 77\*K by the photoionization of TMPD, using pulses of 3471A light from 3 ruby laser. Time dependent absorption spectra are observed which are compared to similar data obtained by pulse radio!ysis. It is concluded that similar electr