𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Decay of trapped electrons by tunnelling to scavenger molecules in low-temperature glasses

✍ Scribed by M. Tachiya; A. Mozumder


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
418 KB
Volume
28
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


The decay of trapped electrons'by turinelling to scavenge; molecules is investigated theoretictiy.

An e&t expression has been derived which gives an exporqtiat decrease of.the.trapped ckktron yiekwith the scavenger concintration at any given time.

,.. ' .' ..

Recently several workers [l-5] have mvbked

,electron tunnelling to explain the decay of trapped '. electrons in glassy,media in the presence of scaven-:_ P(I)=~exp[+(T;)!I 1. -,. '... (I),' .' ,gers'. Some simplifjed calculations have been made-1 _ .. '.


πŸ“œ SIMILAR VOLUMES


Do trapped electrons tunnel to scavenger
✍ J. Kroh; E. Romanowska; Cz. Stradowski πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 202 KB

It is suggested that electrons trapped in irradiated 95% alcohol $ssse~ (+ 5% HZO) do not r-et ~vith the scwenger IIIO[ecules and probably recombine with geminate cations. The scavenging has been interpreted in terms of dry etectrort lX%TCfiOll. There are many indications of the important role of tu

Yields of trapped electrons in pulse irr
✍ G.V. Buxton; K. Kawabata; G.A. Salmon πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 205 KB

## Pulse radiolysis of deuterated aqueous Liclglasses at temperatures in the range 6 K to 70 K show that the yield G(eiR) of infrared absorb-electrons (em) inaeases sharpIy as the temperature is lowered when [LEl] > 10 hf. Under these conditions the yield of visible absorbing electrons (e--,& decr

Application of non-photochemical hole bu
✍ M.C. Edelson; J.M. Hayes; G.J. Small πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 English βš– 258 KB

One-photon non-photochemical hole burning (NPHB) is shown to be a viable method for producing narrow-line twophoton spectra of molecules in solution at low temperature. The TPE spectrum of phenanthrene at 2 K in a glassy medium is presented and is shown to manifest one-photon NPHB effects.