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Photoinitiated anionic coordination polymerization of epoxides, a novel polymerization process

โœ Scribed by Fukuchi, Yoshihisa; Takahashi, Tamotsu; Noguchi, Hiromichi; Saburi, Masahiko; Uchida, Yasuzo


Book ID
127298709
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
802 KB
Volume
20
Category
Article
ISSN
0024-9297

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Lanthanoid isopropoxide as a novel initi
โœ Naoko Fukuwatari; Hiroshi Sugimoto; Shohei Inoue ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 390 KB

Lanthanum isopropoxide was found to serve as a novel anionic initiator for the polymerization of hexyl isocyanate affording poly(hexy1 isocyanate) with very high molecular weight (M, > lo6) under appropriate conditions. Other lanthanoid alkoxides, such as samarium, ytterbium and yttrium isopropoxide