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A Novel Living Coordination Polymerization of Methoxyallene by .pi.-Allylnickel Catalyst

โœ Scribed by Tomita, Ikuyoshi; Kondo, Yukiko; Takagi, Koji; Endo, Takeshi

Book ID
126034284
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
182 KB
Volume
27
Category
Article
ISSN
0024-9297

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A novel living coordination polymerizati
A novel living coordination polymerization of alkoxyallenes by a ฯ€-allylnickel catalyst [1]
โœ I. Tomita; Y. Kondo; K. Takagi; T. Endo ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 411 KB ๐Ÿ‘ 1 views

A coordination polymerization of alkoxyallenes (2a-2f) by the [q3-(allyl)NiOCOCF3] (1) /PPh, system was carried out to obtain a polymer (3) bearing exomethylenes on the main chain. The structure of the obtained polymer was confirmed by 'H-, "C-NMR and IR spectra, and was revealed to consist of two u