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A Novel Living Coordination Polymerization of Phenylallene Derivatives by π-Allylnickel Catalyst

✍ Scribed by Takagi, Koji; Tomita, Ikuyoshi; Endo, Takeshi


Book ID
125940861
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
285 KB
Volume
30
Category
Article
ISSN
0024-9297

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A novel living coordination polymerizati
✍ I. Tomita; Y. Kondo; K. Takagi; T. Endo 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 411 KB 👁 1 views

A coordination polymerization of alkoxyallenes (2a-2f) by the [q3-(allyl)NiOCOCF3] (1) /PPh, system was carried out to obtain a polymer (3) bearing exomethylenes on the main chain. The structure of the obtained polymer was confirmed by 'H-, "C-NMR and IR spectra, and was revealed to consist of two u