The block copolymerization of allene derivatives (3A-3D) with 1,3-butadiene (2) by [(allyl)NiOCOCF 3 ] 2 (1) is described. For instance, the living coordination polymerization of phenylallene (3A, 50 equiv) starting from the living poly(2), which was prepared by the polymerization of 2 (160 equiv) b
✦ LIBER ✦
Block copolymerization of alkoxyallenes with phenylallene by the living coordination system with π-allylnickel catalyst
✍ Scribed by Koji Takagi; Ikuyoshi Tomita; Takeshi Endo
- Book ID
- 106002274
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 553 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0170-0839
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A living block copolymerization of allene derivatives with 1-phenylethyI isocyanide (3) using [(ally l) NiOCOCF~]2 ( 1 ) is described. After complete polymerization of allene monomers such as rz-octyloxyallene (2A) with 1, further addition of 3 to the reaction system yielded the corresponding block