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Living coordination polymerization of end-allenyloxy poly(ethylene glycol) macromonomer by a π-allylnickel catalyst

✍ Scribed by Masanori Taguchi; Ikuyoshi Tomita; Yasuhiko Yoshida; Takeshi Endo


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
76 KB
Volume
201
Category
Article
ISSN
1022-1352

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✍ I. Tomita; Y. Kondo; K. Takagi; T. Endo 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 411 KB

A coordination polymerization of alkoxyallenes (2a-2f) by the [q3-(allyl)NiOCOCF3] (1) /PPh, system was carried out to obtain a polymer (3) bearing exomethylenes on the main chain. The structure of the obtained polymer was confirmed by 'H-, "C-NMR and IR spectra, and was revealed to consist of two u