The Iiis~ ptIoIoclccIron hnd of I~C Ct!2011 radiwl has been obscrvcd will1 a mulIidctccIor phoIoclccIron spccrromcrcr. It cxhibitcd clear vibrational sIrucIurc in IWO vibrdIiona1 modes which wcrc assigned IO cscirarion of the C-O stretch and Cl11 dcformaIion mode in Ihc ion. 'I'hc vcrticll and adiab
Photoelectron spectroscopy and photochemistry of tetracyanoethylene radical anion in the gas phase
β Scribed by Khuseynov, Dmitry; Fontana, Matthew T.; Sanov, Andrei
- Book ID
- 120468243
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 730 KB
- Volume
- 550
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
processes has been described for the reactions of some halogen-1993). With respect to radical anions in the gas phase, a substituted carbene radical anions with the methyl ester of trifluoroacetic acid and dimethyl carbonate. The structural charac-more limited number of reports has appeared irrespec
200 mL) was acidified with 3 drops of 32% HCI and stirred for 15 min at 50Β°C (exclusion of light). After extraction with CH,CI,, the organic phase was dried (Na,SO,) and purified on silica gel (20 8). After removal of the solvent there remained 0.53 g (72%) of a crystalline product. For further puri