Structure and Reactivity of Benzoylnitrene Radical Anion in the Gas Phase
β Scribed by Wijeratne, Neloni R.; Wenthold, Paul G.
- Book ID
- 127051854
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 157 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
processes has been described for the reactions of some halogen-1993). With respect to radical anions in the gas phase, a substituted carbene radical anions with the methyl ester of trifluoroacetic acid and dimethyl carbonate. The structural charac-more limited number of reports has appeared irrespec
200 mL) was acidified with 3 drops of 32% HCI and stirred for 15 min at 50Β°C (exclusion of light). After extraction with CH,CI,, the organic phase was dried (Na,SO,) and purified on silica gel (20 8). After removal of the solvent there remained 0.53 g (72%) of a crystalline product. For further puri
## Abstract The reactions of metal carbonyl anions (M(CO)~__n__~^β^; M = Cr, Mn and Fe; __n__ = 1β3) with __n__βheptane, water and methanol were studied with use of a Fourier transform ion cyclotron resonance (FTβICR) mass spectrometer equipped with an external ion source. The M(CO)~__n__~^β^ ions