✦ LIBER ✦

Observation of the CH2 OH radical in the gas phase by vacuum ultraviolet photoelectron spectroscopy

✍ Scribed by J.M. Dyke; A.R. Ellis; N. Jonathan; N. Keddar; A. Morris

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 371 KB
Volume: 111
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85492-5

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✦ Synopsis

The Iiis~ ptIoIoclccIron hnd of I~C Ct!2011 radiwl has been obscrvcd will1 a mulIidctccIor phoIoclccIron spccrromcrcr. It cxhibitcd clear vibrational sIrucIurc in IWO vibrdIiona1 modes which wcrc assigned IO cscirarion of the C-O stretch and Cl11 dcformaIion mode in Ihc ion. 'I'hc vcrticll and adiabatic ionization cncrgics of the band wcrc mcasurcd as 8.14 z 0.01 and 7.56 2 0.01 cV respectively. Use of ttrc httcr value. cogcthcr wiCh fhc well cstoblishcd hc;lc of forma&m of ctlc ion. allous the hccrl of formalion of rtlc ncuu;ll rnolcculc, Aff?t29Sj (CtilOli).

IO bc csIim;lIcd 3s -0.25 i 0.13 cV.

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