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The UV absorption spectra and kinetics of the self reactions of CH2ClO2 and CH2FO2 radicals in the gas phase

✍ Scribed by Philippe Dagaut; Timothy J. Wallington; Michael J. Kurylo

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 583 KB
Volume: 20
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550201006

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✦ Synopsis

The ultraviolet absorption spectra of chloromethylperoxy and fluoromethylperoxy radicals, CH2C10z and CH2F02, and the kinetics of their respective self reactions have been studied in the gas phase using a flash photolysis technique. The absorption spectra for both radicals were quantified over the wavelength range 210 and 290 nm. The measured absorption cross-sections

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