Photodissociation of o-dichlorobenzene at 266 nm
β Scribed by Rong-Shun Zhu; Hong Zhang; Guang-Jun Wang; Xi-Bin Gu; Ke-Li Han; Guo-Zhong He; Nan-Quan Lou
- Book ID
- 108430861
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 199 KB
- Volume
- 248
- Category
- Article
- ISSN
- 0301-0104
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## Abstract In a crossed laserβmolecular beam study of nitromethane it was found that the excitation of nitromethane at 266 nm did not yield dissociation products under collisionβfree conditions. When a small cluster of nitromethane was excited at the same frequency, the product was seen only at en
We report a picosecond pump-probe study of the UV photolysis of gaseous dimethylnitramine. After photolysis by picosecond laser pulses at 266 nm, efficient monophotonic collision-free photodissociation occurs within 6 ps. NO\* fragments are formed in the ground electronic state and in a fluorescent