We have previously described the conditions by which peptide synthesis by the solid-phase fragment condensation approach can be carried out using crown ethers as non-covalent protection for the N alpha-amino group. Here we demonstrate that the procedure can be extended to large, partially protected
Photodissociation of Non-Covalent Peptide-Crown Ether Complexes
✍ Scribed by Jeffrey J. Wilson; Gregory J. Kirkovits; Jonathan L. Sessler; Jennifer S. Brodbelt
- Book ID
- 108158424
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 168 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1044-0305
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The intromolecular charge transfer spectra of six crown ethers, namely 15C5, B15C5, 18C6, B18C6, DB18C6 and DC18C6 acting as donors, and iodine, acting as an acceptor, were studied in the UV-vis region in methylene chloride. The complex formation constants were computed. The results indicate that bo
## Abstract **Die Krone muss passen**: Kationische Ge^II^‐Komplexe lassen sich mit Kronenethern zum Stabilisieren und Schützen des Germaniumzentrums herstellen. Drei verschiedene Kronenether wurden eingesetzt: [12]Krone‐4 (siehe Struktur, Ge türkis, O rot, C grau), [15]Krone‐5 und [18]Krone‐6. Die