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Molecular complexes of crown ethers—Part 1. Complexes between crown ethers and iodine

✍ Scribed by SalmanR. Salman; SabriM. Al-Marsumi

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
25 KB
Volume
49
Category
Article
ISSN
1386-1425

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✦ Synopsis

The intromolecular charge transfer spectra of six crown ethers, namely 15C5, B15C5, 18C6, B18C6, DB18C6 and DC18C6 acting as donors, and iodine, acting as an acceptor, were studied in the UV-vis region in methylene chloride. The complex formation constants were computed. The results indicate that both the oxygen atom and the aromatic ring contribute to the value of the formation constant Kc.

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