The reaction IzM + hu-12( B) + M is studied followmg excitation of the 12M cluster above its B state dissoctation limit with M being the diatomics Hz, Nz, 0, and I\*. Dispersion of the iodine fluorescence allows for the determination of the relative populations of a number of the vibrational levels
Photodissociation of Hydrogen Halide Molecules in Different Cluster Environments
β Scribed by Udo Buck
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 48 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
π SIMILAR VOLUMES
Calculations of the probabilities of vibrational transitions PI\_ 0 have heen made for HX molecules (X is F. Cl, Br, I) for their collisions with HX, H2, He, Ar. The rotational anisotropy of the intermolecular potential was taken into account. A diagram of electronic density for the HF molecules was
## lnknctmn of Hz with a IiUuum meta surface stmuhted by eight LI atoms ~studied usmg the DIM method. Two vartables arc cwnined. the &stance of Hz from the surface and the H-H separation. The adsorption proceeds ababatwlly. As-SOCIP~IVC chenusorption IS prcdtcted to be energctlcally more favounbl