Secondary isotope effects were examined in the loss of methyl from the molecular ions of C,D,OC,H, and CD,CH,OC,H, for ion source processes and collisional activation (CA) processes. In the ion source loss of CH, was slightly favored over loss of CD, , but in CA the CH, loss was favored to a much la
β¦ LIBER β¦
Hydrogen isotope effects in the photodissociation of C2H2 and C2D2 molecules superexcited at 16.85 and 21.22 eV
β Scribed by Toshio Ibuki; Yasuhiko Horie
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 478 KB
- Volume
- 196
- Category
- Article
- ISSN
- 0009-2614
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## Abstract Recently, we have discovered the unusual inverse temperature dependence of the kinetic isotope effect (KIE) for the OH + __c__βC~6~H~12~/__c__βC~6~D~12~ reaction in water. Temperature increase causes a KIE increase; this is valid for both the Fenton system (I) and the HOONOο£ΏH~2~O system