Photodissociation of Gaseous NCl 3 at 193 and 249 nm †
✍ Scribed by Coombe, R. D.; Gilbert, J. V.; Beaton, S. S.; Mateljevic, N.
- Book ID
- 126993067
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 110 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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The 193 nm photodissociation of the isotopomers SOz, SO: and SOO' (with O\*= '\*O) was studied by high-resolution photofragment translational spectroscopy. The translational energy distributions P(&) of the fragment pairs SOtO, SO'tff, SOt(T and SO\*+0 were determined from systematic analysis of the
Photodissociation of H$ has been studied at 193.3 nm using H atom photofragment-translational speclroscopy with massspectrometric detection. H t HS( v) product branching ratios are reported which are not in quantitative agreement with other recent experimental results. Secondary photodissociation of
We have generated a cold beam of the highly corrosive sulfur trioxide SO3 and have studied its photodissociation at 193 nm by photofragment translational spectroscopy, The spin-allowed process SO3( g 'A{) + hv --+ SOs( ji 'Al ) + 0( 'D) was found to be the primary dissociation channel. A part of the