✦ LIBER ✦

Photodissociation of CFCl3 at 193 nm investigated by photofragment translational spectroscopy

✍ Scribed by Peter Felder; Caspar Demuth

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 549 KB
Volume: 208
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)80070-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Photodissociation of SO3 at 193 nm inves

Photodissociation of SO3 at 193 nm investigated by photofragment translational spectroscopy

✍ M.-A. Thelen; J.Robert Huber 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 507 KB

We have generated a cold beam of the highly corrosive sulfur trioxide SO3 and have studied its photodissociation at 193 nm by photofragment translational spectroscopy, The spin-allowed process SO3( g 'A{) + hv --+ SOs( ji 'Al ) + 0( 'D) was found to be the primary dissociation channel. A part of the

Photodissociation of CF2BrCl at 193 nm i

Photodissociation of CF2BrCl at 193 nm investigated by photofragment translational spectroscopy

✍ G. Baum; J.Robert Huber 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 501 KB

The photodissociation of the halon CF&Cl has been studied by the time-of-flight crossed-laser molecular-beam method at 193 nm. Two primary decays are operative, the dominant one yielding CFsCl+Br (DA') = 63.5 f 3 kcaJ/mol) with Br( 'P1,s): Br(\*P,,,) ~2: I and the second one CF,Br+CI (06s) =78 &4 kc

Photodissociation of CF2Cl2 at 193 nm in

Photodissociation of CF2Cl2 at 193 nm investigated by phtofragment translational spectroscopy

✍ G. Baum; J. Robert Huber 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 346 KB

Photodissociation of CH2BrCl at 248 and

Photodissociation of CH2BrCl at 248 and 193 nm investigated by translational spectroscopy

✍ W.B. Tzeng; Y.R. Lee; S.M. Lin 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 449 KB

The photodissociation of CH2BrCl at 248 and 193 nm has been studied by translational spectroscopy. Both the product translational energy distribution and the anisotropy parameter were derived from the measured time-of-flight spectra. Results show that at 248 nm, CHzBrCl exclusively dissociates to CH

Photodissociation of CBrCl3 at 248 nm by

Photodissociation of CBrCl3 at 248 nm by translational spectroscopy

✍ Y.R. Lee; W.B. Tzeng; Y.J. Yang; Y.Y. Lin; S.M. Lin 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 456 KB

The photodissociation of CBrCls at 248 nm has been studied by translational spectroscopy. The primary dissociation process is shown to produce exclusively CC& and Br with an average translational energy of 20 kcal/mol. From the measured anisotropy parameter /I= -0.4f0.2, CBrCls undergoes a simple C-

Photodissociation of S2Cl2 at 308 nm by

Photodissociation of S2Cl2 at 308 nm by translational spectroscopy

✍ Y.R. Lee; C.L. Chiu; S.M. Lin 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 551 KB

The photodissociation of f&Cl, at 308 urn has been studied by the crossed laser-molecular beam technique. Both the product translational energy distribution and the anisotropy parameter j? were derived from the measured time-of--flight spectra. Results show that S&l2 undergoes a simple S-Cl bond sci