✦ LIBER ✦

Photocrosslinking of chlorinated polydimethylsiloxanes

✍ Scribed by Hiroshi Inoue; Shigemi Kohama

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 487 KB
Volume: 32
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.1986.070320305

No coin nor oath required. For personal study only.

✦ Synopsis

Photocrosslinking behavior of chlorinated polydimethylsiloxanes (CPDMS) has been studied. It was found that the viscous CPDMS were readily crosslinked to form the rubberlike materials on irradiation from a high pressure mercury lamp. The crosslinking mechanism was proposed on the basis of infrared spectroscopy. It was suggested that the photolysis of the carbonchlorine bond induced by the ultraviolet irradiation is a primary step for crosslinking, and is followed by mutual combination of SiCH2. radicals, eventually, to form the crosslinked C PDMS. The effect of halogens and atmosphere on the crosslinking was also discussed.

📜 SIMILAR VOLUMES

Synthesis of photocrosslinkable fluorina

Synthesis of photocrosslinkable fluorinated polydimethylsiloxanes: Direct introduction of acrylic pendant groups via hydrosilylation

✍ Bernard Boutevin; Francine Guida-Pietrasanta; Amédée Ratsimihety 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB

Supercooling of polydimethylsiloxane

✍ J. D. Helmer; K. E. Polmanteer 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 290 KB

Photocrosslinking of stilbene-modified p

Photocrosslinking of stilbene-modified polymers

✍ F. A. Stuber; Henri Ulrich; Durvasula V. Rao; A. A. R. Sayigh 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 426 KB 👁 1 views

Nonpollutative Chlorination and Chlorina

Nonpollutative Chlorination and Chlorinating Oxidation of Phenols

✍ Dipl.-Chem. Hans Lübbecke; Prof. Dr. Peter Boldt 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 153 KB

Chlorination of polystyrene

✍ Robert K. Jenkins; Norman R. Byrd; James L. Lister 📂 Article 📅 1968 🏛 John Wiley and Sons 🌐 English ⚖ 320 KB

Chlorination of Cyclooctatetraene

✍ Prof. Dr. R. Huisgen; Dr. G. Boche; Dipl.-Chem. W. Hechtl; H. Huber 📂 Article 📅 1966 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB

Only two examples of cycloaddition to ynamines have so far been reported 121. By 1,3-dipolar cycloaddition under the conditions described previously 131, ynamines readily afford dialkylamino-substituted heterocycles ( I ) (Table 1). The structure of the products follows from analytical data and in a