๐”– Bobbio Scriptorium
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Chlorination of Cyclooctatetraene

โœ Scribed by Prof. Dr. R. Huisgen; Dr. G. Boche; Dipl.-Chem. W. Hechtl; H. Huber


Publisher
John Wiley and Sons
Year
1966
Tongue
English
Weight
213 KB
Volume
5
Category
Article
ISSN
0044-8249

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โœฆ Synopsis


Only two examples of cycloaddition to ynamines have so far been reported 121. By 1,3-dipolar cycloaddition under the conditions described previously 131, ynamines readily afford dialkylamino-substituted heterocycles ( I ) (Table 1). The structure of the products follows from analytical data and in analogy to earlier results [31.


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Ial Compound (61. tbl Compound (5). carboxylation with lead tetraacetate in the presence of pyridine [21. Hydroxylation of (2) with performic acid gave a mixture of glycols, consisting mainly of cis-1,2,3,4-dibenzocis-configuration of this glycol was shown by its identity with the compound obtained