1,2,3,4-Dibenzo-cyclooctatetraene

✍ Scribed by Prof. Dr. Emanuel Vogel; Dr. W. Frass; Dipl.-Chem. J. Wolpers

• Publisher: John Wiley and Sons
• Year: 1963
• Tongue: English
• Weight: 119 KB
• Volume: 2
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.196306251

✦ Synopsis

Ial Compound (61. tbl Compound (5).

carboxylation with lead tetraacetate in the presence of pyridine [21. Hydroxylation of (2) with performic acid gave a mixture of glycols, consisting mainly of cis-1,2,3,4-dibenzocis-configuration of this glycol was shown by its identity with the compound obtained from and Os04. This unusual cis-hydroxylation with performic acid is probably due to a ( ' ) cycloocta-l,3-diene-6,7-diol (3) (m.p. l69--170 "C) [3]. The