Synthesis of photocrosslinkable fluorinated polydimethylsiloxanes: Direct introduction of acrylic pendant groups via hydrosilylation

A solvent-free method for the synthesis

A solvent-free method for the synthesis of block copolymers with fluorinated pendant groups by a hydrosilylation reaction

✍ J. D. Jeyaprakash S. Samuel; R. Dhamodharan; Christopher K. Ober 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 119 KB 👁 2 views

A solvent-free method for the hydrosilylation of pendant double bonds in block copolymers is reported in this article. An anionically prepared block copolymer, poly(styrene-b-1,2-butadiene), was heated with 1H,1H,2H,2H-perfluorooctyldimethylhydrosilane in the presence of a nonacidic platinum catalys