Photochromic and thermochromic spiranes. 19. 2-thioxo-3-phenyl-5,5-diivietiiylspiro (1,3-oxazolidine-4,2′-[2h]chromenes)
✍ Scribed by B. S. Luk'yanov; N. B. Ivanov; L. E. Nivorozhkin; V. I. Minkin; G. S. Borodkin
- Publisher
- Springer US
- Year
- 1995
- Tongue
- English
- Weight
- 474 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-3122
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.002 A Ê R factor = 0.045 wR factor = 0.099 Data-to-parameter ratio = 14.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
All interatomic distances in the title compound, C~13~H~15~N~3~O~2~S, are normal. The 1,2,4-triazole ring is planar and is inclined at 46.50 (6)° to the phenyl ring. The ethoxycarbonylmethyl group is also close to being planar and is inclined at 87.54 (9)° to the 1,2,4-triazole ring. The crystal was
In the title complex, [Sn(C 6 H 5 ) 3 (C 8 H 7 N 4 S)], all bond lengths and angles show normal values. The Sn centre is fourcoordinated by three C atoms [Sn-C 2.119 (6)-2.133 (6) A ˚] and one N atom [Sn-N 2.107 (5) A ˚] in a distorted tetrahedral geometry. The crystal packing exhibits no classical
Alkylation of 1-(3,4-Disubstituted Phenyl)-2-thioxo-1,2,5,6tetrahydropyrimidin-4(3H)-ones. -Alkylation of the title compounds (I), (VI), and (IX) results in the formation of S-and N-methylated derivatives. S-methylated products (III), (VII), and (X) are always the major products. In all cases, meth