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Photochemistry of the Phthalimide System, 37. Thiazacycloalkanols by Photocyclization ofS-SubstitutedN-(Thioalkyl)phthalimides

✍ Scribed by Sato, Yasuhiko ;Nakai, Hideo ;Wada, Masao ;Mizoguchi, Tomishige ;Hatanaka, Yasumaru ;Migita, Yoshihiro ;Kanaoka, Yuichi

Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 876 KB
Volume: 1985
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.198519850602

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✦ Synopsis

Abstract

N‐Substituted phthalimides (1, 2) possessing a terminal thioether function in their side chain were irradiated with a high‐pressure mercury lamp to give a variety of thiazacycloalkanol derivatives (3, 7, 9–13, 16, 17) with favored γ‐, δ‐, ϵ‐, and ζ‐hydrogen abstractions (Table 1), in moderate to fairly good yields.

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