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Photochemistry of the phthalimide system. V photocyclization of the phthalimides with a sulfide chain: synthesis of aza-cyclols by δ, ε, and ς hydrogen abstraction

✍ Scribed by Yasuhiko Sato; Hideo Nakai; Hiroshi Ogiwara; Tomishige Mizoguchi; Yoshihiro Migita; Yuichi Kanaoka

Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
196 KB
Volume
14
Category
Article
ISSN
0040-4039

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Photochemistry of the Phthalimide System
Photochemistry of the Phthalimide System, 44. Photoinduced Reactions, 122. Regioselective Remote Photocyclization: Examples of a Photochemical Macrocyclic Synthesis with Sulfide-Containing Phthalimides
✍ Hatanaka, Yasumaru ;Sato, Yasuhiko ;Nakai, Hideo ;Wada, Masao ;Mizoguchi, Tomish 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 900 KB

## Abstract __S__‐Substituted __N__‐(thioalkyl)phthalimides 2 underwent photocyclization to give azathiacyclols, up to 16‐membered ring compounds, in good yields. The cyclization occurred between an imide carbonyl group and a terminal sulfide group located in a remote position from the carbonyl gro