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A synthetic approach to crown ether analogs by the remote photocyclization with a pai system of phthalimide and methylthio groups

✍ Scribed by Masao Wada; Hideo Nakai; Yasuhiko Sato; Yuichi Kanaoka


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
214 KB
Volume
23
Category
Article
ISSN
0040-4039

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✦ Synopsis


Upon irradiation a homologous series of certain phthalimides (2a-c) possessing a -terminal sulfide function in their N-ply-ether side chain undergo regioselective remote photocyclization affording seven to fifteen-membered crown ether analogs (3a

-c

) in nwderate yields.