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Photochemistry of bicyclo[6.2.0]decan-9-ones in solution

✍ Scribed by D.M. McDaniel; N.J. Turro

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
218 KB
Volume
13
Category
Article
ISSN
0040-4039

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## Abstract On irradiation (300β€…nm) in the solid state, the title compound **8** affords tricyclo[3.3.1.1^3,7^]decan‐2‐one (=adamantan‐2‐one; **9**) selectively __via__ [4+2] cycloreversion. A similar result is obtained on photolysis in solution (MeCN or acetone), also in the presence of added alke