✦ LIBER ✦

Photochemistry of bicyclo[3.3.1]nonenes

✍ Scribed by M. Kawanisi; H. Kato

Book ID: 104248671
Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 127 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97812-8

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✦ Synopsis

Recent report (1) on photochemical polar addition reaction of methanol or 2propanol to a bridged bicyclic olefin, bicyolo(3.2.l)oct-2-ene, has prompted US to report results on the polar addition of acetic acid to the similar system, bicyclo(3.3.l)non-2-ene and its derivative, possibly accompanying 3,7-hydride shift.

When a 1% acetic acid-benzene solution of I wae irradiated with unfiltered high premsure mercury arc for 48 hr under atmosphere of N2, two isomerio adducts,

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