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Bridgehead-Substituted Bicyclo[3.3.1]nonenes and Their Benzo and Dibenzo Derivatives

✍ Scribed by Shi, Xiaolian; Miller, Bernard

Book ID
118273884
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
447 KB
Volume
60
Category
Article
ISSN
0022-3263

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✍ Konrad B. Becker; Jacques L. Chappuis πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 German βš– 700 KB

## Abstract The synthesis of 1‐bicyclo[3.2.2]nonene **(2)** and of 1 (7)‐bicyclo [3.2.2]nonene **(3)**, two isomeric bridged (__E__)‐cycloheptenes, by intramolecular __Wittig__ reaction is described. These β€˜__Bredt__ olefins’ could not be isolated, but dimerized rapidly. In both cases, the main pro