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Conformational equilibria and rates of bridgehead proton exchange for 3,3-dimethyl-2-bicyclo[3.3.1]nonanone and 3,3-dimethyl-7-bicyclo[3.3.1]nonen-2-one

โœ Scribed by Marvell, Elliot N.; Gleicher, Gerald Jay; Sturmer, David; Salisbury, Kirby


Book ID
127041129
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
724 KB
Volume
33
Category
Article
ISSN
0022-3263

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Synthesis of 1-Bicyclo [3.2.2]nonene and
โœ Konrad B. Becker; Jacques L. Chappuis ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 700 KB

## Abstract The synthesis of 1โ€bicyclo[3.2.2]nonene **(2)** and of 1 (7)โ€bicyclo [3.2.2]nonene **(3)**, two isomeric bridged (__E__)โ€cycloheptenes, by intramolecular __Wittig__ reaction is described. These โ€˜__Bredt__ olefinsโ€™ could not be isolated, but dimerized rapidly. In both cases, the main pro