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Synthesis of Polysubstituted Bicyclo[3.3.1]nonane-3,7-diones from Cyclohexa-2,5-dienones and Dimethyl 1,3-Acetonedicarboxylate

✍ Scribed by Pelayo Camps; Albert González; Diego Muñoz-Torrero; Montserrat Simon; Adriana Zúñiga; Miriam A. Martins; Mercè Font-Bardia; Xavier Solans


Book ID
108370951
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
215 KB
Volume
56
Category
Article
ISSN
0040-4020

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Synthesis of endo-1,3-dimethyl-2,9-dioxa
✍ Peter Mohr; Christoph Tamm 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 112 KB

The title compound has been synthesized stereoselectively based on a new methodology for the construction of erythro-1,3-diols. Endo-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane (11, first isolated by Heemann and Francke in 1976 from Norway spruce attacked by the ambrosia beetle (Tgypodendron Lineatum