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Photochemistry of 3-cyano-4,4-dimethyl-2,5-cyclohexadienone. Evidence for selectivity during the photorearrangement of unsymmetric cyclohexadienones

✍ Scribed by Stille, J. K.; Rettig, T. A.; Kuemmerle, E. W.


Book ID
127389293
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
824 KB
Volume
41
Category
Article
ISSN
0022-3263

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## Abstract Filicinic acid (5) was prepared in 75‐80% overall yield from 4,4‐dimethyl‐2‐cyclohexenone (1). The key intermediate, tetrachlorodienone 2, underwent facile substitution of both β‐chlorine substituents by methoxide affording the bis enol ether 3 which was converted into dichlorofilicinic