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New Substituent Effects of the Trimethylsilyl Group: Photochemistry of 3-Trimethylsilyl-2,5-cyclohexadienones and Preparation of 4-Alkylidenecyclopentenones

โœ Scribed by Schultz, Arthur G.; Lockwood, Larry O.


Book ID
126120525
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
108 KB
Volume
65
Category
Article
ISSN
0022-3263

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A convenient method for the preparation
โœ Fumie Sato; Hiroshi Kanbara; Youichi Tanaka ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

Hydromagnesiation of 3-trimethylsilyl-2-propyn-l-01 (&) followed by reaction with aldehydes or ketones affords (E)-3-trimethylsilyl-2-alken-1,4-diols (&), which can be readily dehydrated to 3-trimethylsilyl-2,5-dihydrofurans (3) by treatment with BF30Et2. The compounds 3\_ are converted to furans (5