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Photochemical Transformations of a β,γ-Epoxy Ketone 1

✍ Scribed by Padwa, Albert

Book ID
125418650
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
377 KB
Volume
87
Category
Article
ISSN
0002-7863

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The reaction of trialkylstannylmethyllit
The reaction of trialkylstannylmethyllithium with α,β-epoxy ketones. A preparative method of β, γ-unsaturated ketones by homologation of α, gb-unsaturated ketones
✍ Tadashi Sato; Toshihiro Kikuchi; Norio Sootome; Eigoro Murayama 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 224 KB

a,@-Epoxy ketones 2\_, upon treatment with two equivalents of trialkylstannylmethyllithium 1, afforded cyclopropanols 2 as a single product in acyclic system, and a mixture of cyclopropanols 2 and methylene 1,2-diols 2 in cyclic system. Under acidic conditions, the cyclopropanols gave p,y-unsaturate