Photochemical transformation of metal-free phthalocyanine in a Shpol'skii matrix
β Scribed by Chen Wen-Hsiung; Klaus E. Rieckhoff; Eva-Maria Voigt
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 947 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A~tract--Solution photochemistry of some (N,N-di-n-butyldithiocarbamato) complexes and of the metal-free dithiocarbamate ligands has been used to investigate their role in the photo-oxidation of polyolefins. Transient absorption spectra were recorded for tetramethyl thiuram disulphide at around 600
It contains detailed experimental procedures for the synthesis and the rearrangement of thiocarbamates, 1 H and 13 C NMR spectroscopic data, MS, and FTIR for new compounds, as well as total energy and Cartesian coordinates for each optimized stationary point at the reaction hyper surfaces. Scheme 1.
I hc kincllc inc~iwi-eiiieiif\ &&ere performed under pseudo-first-oi-dcr conditions a t I M ioiiic ~Ireiiflli (NaNO,). Solutions of the ligand end the coniplexes were hullcred ~i t l i pho\phatl: at pH =7. The rate of the reaction is independent of the pH 111 thi\ irangc ( I ] The p \'iiluc?, for th