Metal-Free Transformation of Phenols into Substituted Benzamides: A Highly Selective Radical 1,2-O→C Transposition in O-Aryl-N-phenylthiocarbamates

✍ Scribed by Abdulkader Baroudi; Phillip Flack; Prof. Igor V. Alabugin

• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: English
• Weight: 312 KB
• Volume: 16
• Category: Article
• ISSN: 0947-6539
• DOI: 10.1002/chem.201002303

✦ Synopsis

It contains detailed experimental procedures for the synthesis and the rearrangement of thiocarbamates, 1 H and 13 C NMR spectroscopic data, MS, and FTIR for new compounds, as well as total energy and Cartesian coordinates for each optimized stationary point at the reaction hyper surfaces. Scheme 1. Equation (1): O!C Radical transposition triggered by the Bergman cyclization of enediynes. Equation (2): Radical transformation of diaryl thiocarbonates into benzoate esters.